The synthesis of cubane-1,4-dicarboxylic acid has been scaled up and is now conducted in small pilot plants by Fluorochem in California and EniChem Synthesis in Milan. It is now being made …

Synthesis of Phosphine-Functionalized Silicon Cubane and Its Oxidative Addition, Giving a Bis(silyl)copper Complex. Inorganic Chemistry 2023, 62 (6) , 2503-2507. …

Herein, we demonstrate a robust approach to 5 that allows the straightforward multigram-scale synthesis of 1,3-cubane diester 11 as well as various novel 1,3-disubstituted cubane derivatives.

2023年5月11日 · Cubane is a charming contender to benzene as both share close geometries, and are called bioisosteres. If functionalised at a few or all the carbon atoms, they have the …

2023年5月31日 · The approach exploits a readily available enone intermediate previously used for the synthesis of 1,4-disubstituted cubanes, by introducing a novel Wharton transposition to …

objective of this research is to develop new methods for the functionalization of the cubane nucleus and to synthesize energetic cubanes for use as high energy propellants, explosives, …

2015年6月23日 · Synthesis of Phosphine-Functionalized Silicon Cubane and Its Oxidative Addition, Giving a Bis(silyl)copper Complex. Inorganic Chemistry 2023 , 62 (6) , 2503-2507.

2023年4月4日 · Here we report expedient routes to 1,3- and 1,2-disubstituted cubane building blocks using a convenient cyclobutadiene precursor and a photolytic C–H carboxylation …

The recent renaissance of cubane chemistry, triggered by potential applications of the system to the production of high-energy fuels and propellants, has lead to many discoveries including the …

2014年2月2日 · Cubane (C 8 H 8) is a synthetic hydrocarbon molecule that consists of eight carbon atoms arranged at the corners of a cube, with one hydrogen atom attached to each …