Hydrogels, which are soft materials made of water-filled, crosslinked polymer networks, have a wide range of uses, from wound ...
However, the rapid release of CO₂ after gelation limits calcium ion availability, resulting in reduced crosslinking of the alginate chains.
Hydrogels created using carbon dioxide (CO₂) offer a safer alternative to those formed with acidic agents. While most research has focused on pre-gelation conditions affecting hydrogel properties, ...
We demonstrate that progressive gelation initiates along an annular front, isolating a central pool that briefly remains open to particulate advection before gelation completes across the droplet ...
The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.chemmater.4c02460.
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However, the sequence features and mechanisms underlying gel formation and the necessity of gelation for protection have not been demonstrated. Here, we report a mechanism of fibrillization and ...
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